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31.
We obtain expressions for the energy spectrum widths of Rayleigh waves corresponding to their deformational coupling to Fermi and Boltzmann electrons in a two-dimensional layer near the surface of a semibounded solid. We evaluate the nonequilibrium energy of Rayleigh waves that depends on these widths and is caused by the same coupling to the corresponding hot electrons. We show that this energy is independent of the degeneracy degree of the electrons and is given by the mean energy of free Rayleigh waves heated up to temperature of the electrons. We find conditions under which the thermodynamics is determined by this nonequilibrium energy of Rayleigh waves in films of a certain thickness with Fermi electrons near the surface and by the equilibrium energy of bulk phonons in thicker samples. All the results are obtained using the Keldysh diagram technique applied to the case of semibounded media. 相似文献
32.
Hong-Xing Zheng Dao-Yin Yu 《International Journal of Infrared and Millimeter Waves》2005,26(9):1343-1353
In this paper, a very useful numerical technique has been developed for analyzing the transient characteristics of a planar-spiral inductor on-chip. A locally conformal technique and an alternating-direction implicit scheme are applied to the finite-difference time-domain method. A formulation for solving three dimensional Maxwell’s equations is proposed. Using the proposed method, various parameters of the planar-spiral inductors have been analyzed and an equivalent circuit, which includes frequency-independent circuit elements, has been introduced. Highly computational efficiency is implemented. Numerical results show excellent agreement with the measured data over a wide frequency range. 相似文献
33.
双氯芬酸钠与牛血清白蛋白结合反应的特征 总被引:2,自引:0,他引:2
在模拟人体生理条件下,采用荧光光谱和紫外 可见吸收光谱法研究了双氯芬酸钠与牛血清白蛋白的结合反应.实验结果显示,双氯芬酸钠对牛血清白蛋白有较强的荧光猝灭作用,该猝灭过程主要为静态荧光猝灭过程;二者结合常数KLB=2.167×105mol·L-1;二者的结合位置距212位色氨酸2.13nm;同时,由结合反应的热力学参数得出二者作用力主要是氢键或VanderWall's力. 相似文献
34.
WANG Wen zhen * LIU Xin MENG Yi LIAO Dai zheng * JIANG Zong hui YAN Shi ping WANG Geng lin . Department of Chemistry Nankai University Tianjin P. R. China . State Key Laboratory of Coordination Chemistry Nanjing University Nanjijng P. R. China 《高等学校化学研究》2003,19(1)
IntroductionFive- coordinated complexes with d9- configuredcations have received much attention stereochemi-cally,spectrochemically and biologically,and havebeen comprehensively discussed[1] . Usually thereare two stable configurations for the copper( )complexes with five equal coordinating atoms:anapically elongated square pyramid( SP) and a com-pressed trigonal bipyramid( TBP) ,with an obviousenergetic preference for the latter coordination.When the ligands are rigid and provide angular d… 相似文献
35.
36.
富勒烯 (C60 /C70 )与N ,N ,N′ ,N′ 四 (对甲苯基 ) 4,4′ 二胺 1,1′ 二苯硒醚 (TPDASe)间在激光光诱导条件下 ,发生了分子间的电子转移过程 .在可见 -近红外区 ( 60 0~ 12 0 0nm) ,观测到了TPDASe阳离子自由基、富勒烯 (C60 /C70 )激发三线态和阴离子自由基 ,在苯腈溶液中 ,观测瞬态谱测定了电子从TPDASe转移到富勒烯 (C60 /C70 )激发三线态的量子转化产率(ΦTet)和电子转移常数 (Ket) . 相似文献
37.
38.
One of the fundamental factors of the performance of atomic spectrometric methods is the efficiency of sample introduction into flame or plasma. By utilization of the formerly developed hydraulic high-pressure nebulizer, a nebulizer/burner system with solution uptake efficiency of 100% have been worked out. Optimizing operation parameters of nebulizer/burner system, an improvement of 2-12 times was achieved for the signal-to-noise ratio in the flame emission and flame atomic absorption spectrometry, depending on sample flow rate. This nebulizer is especially suitable for development of liquid chromatography-AAS/FES coupled technique for speciation analytical tasks. 相似文献
39.
A. V. Ivanov M. Yu. Tsentalovich E. G. Kogan L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2008,57(8):1676-1679
The chlorination of benzene, toluene, and o-xylene with molecular chlorine in the presence of the phthalocyanine complexes of different structures was studied. The transformations
of the catalysts during the reaction were investigated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1644–1647, August, 2008. 相似文献
40.
A. A. Zazhogin A. P. Zazhogin A. I. Komyak A. I. Serafimovich 《Journal of Applied Spectroscopy》2003,70(6):827-831
Based on the analysis of electronic absorption and luminescence spectra, the processes of complexing in an aqueous solution of uranyl nitrate hexahydrate (UO2(NO3)2·6H2O) on gradual addition of small amounts of acetone have been investigated. In a pure aqueous solution, uranyl exists as the UO2·5H2O complex. It is shown that addition of acetone to the solution leads to displacement of some water molecules from the first coordination sphere of uranyl and formation of uranyl nitrate dihydrate complexes, UO2(NO3)2·2H2O. It has been established that the stability of these complexes is determined by the decrease in both the water activity and the degree of hydration of uranyl and nitrate. This is the result of the local increase in the concentration of the molecules of acetone (due to its hydrophobicity) in those regions of the solution in which there are uranyl and nitrate ions. The experimental facts supporting the proposed mechanism are given. 相似文献